Kinetic studies and predictions on the hydrolysis and aminolysis of esters of 2-S-phosphorylacetates
نویسندگان
چکیده
منابع مشابه
Kinetic studies and predictions on the hydrolysis and aminolysis of esters of 2-S-phosphorylacetates
BACKGROUND Heterobifunctional cross-linking agents are useful in both protein science and organic synthesis. Aminolysis of reactive esters in aqueous systems is often used in bioconjugation chemistry, but it must compete against hydrolysis processes. Here we study the kinetics of aminolysis and hydrolysis of 2-S-phosphorylacetate ester intermediates that result from displacement of bromide by a...
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2010
ISSN: 1860-5397
DOI: 10.3762/bjoc.6.87